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Gallium Arsenide (By Crystallization)
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Tin Arsenide (By Crystallization)
Arsenic
Arsenic information, including Technical Data, Safety Data and its properties, research, applications and other useful facts are discussed below. Scientific facts such as the atomic structure, ionization energy, abundance on Earth, conductivity and thermal properties are included.

Arsenic has numerous applications as a semiconductor and other electronic applications as Indium arsenide, silicon arsenide and tin arsenide. Arsenic is finding increasing uses as a doping agent in solid-state devices such as transistors. Gallium arsenide is used as a laser material to convert electricity directly into coherent light. Arsenic is used in bronzing and for hardening and improving the sphericity of shot. Arsenic is available as metal and compounds with purities from 99% to 99.9999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder.

Arsenic facts, including appearance, CAS #, and molecular formula and safety data, research and properties are

 

  Hydrogen                                 Helium
  Lithium Beryllium                     Boron Carbon Nitrogen Oxygen Fluorine Neon
  Sodium Magnesium                     Aluminum Silicon Phosphorus Sulfur Chlorine Argon
  Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Hydrogen Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton
  Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon
  Cesium Barium Cerium Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury Thallium Lead Bismuth Polonium Astatine Radon
                                     
      Cerium Praseodymium Neodymium Promethium Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium    
      Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawerencium    


(click on an element)
available for many specific states, forms and shapes on the product pages listed to the left. Elemental or metallic forms include pellets, rod, wire and granules for evaporation source material purposes. Nanoparticles and nanopowders provide ultra high surface area which nanotechnology research and recent experiments demonstrate function to create new and unique properties and benefits.

Oxides are available in forms including powders and dense pellets for such uses as optical coating and thin film applications. Oxides tend to be insoluble. Fluorides are another insoluble form for uses in which oxygen is undesirable such as metallurgy, chemical and physical vapor deposition and in some optical coatings. Arsenic is available in soluble forms including chlorides, nitrates and acetates. These compounds are also manufactured as solutions at specified stoichiometries.

Arsenic is a Block P, Group 15, Period 4 element. The electronic configuration is [Ar] 3d10 4s2 4p3. In its elemental form arsenic's CAS number is 1327-53-3. The arsenic atom has a radius of 124.5.pm and it's Van der Waals radius is 185.pm.

All elemental metals, compounds and solutions may be synthesized in ultra high purity (e.g. 99.999%) for laboratory standards, advanced electronic, metallurgy and optical materials and other high technology advantages. Information is provided for stable (non-radioactive) isotopes. Organo-Metallic Arsenic compounds are soluble in organic or non-aqueous solvents. See Analytical Services for information on available certified chemical and physical analysis techniques including MS-ICP, X-Ray Diffraction, PSD and Surface Area (BET) analysis.

Arsenic was first discovered by Early Man.<

French Arsenic German Arsen Italian Arsenico Portuguese Arsênic Spanish Arsénico Swedish Arsenik

Abundance. The following table shows the abundance of arsenic and each of its naturally occurring isotopes on Earth along with the atomic mass for each isotope.

Isotope
Atomic Mass
% Abundance on Earth
As-75
74.921596
100

Safety Data. The safety data for arsenic metal, nanoparticles and its compounds can vary widely depending on the form. For potential hazard information, toxicity, and road, sea and air transportation limitations, such as DOT Hazard Class, DOT Number, EU Number, NFPA Health rating and RTECS Class, please see the specific material or compound referenced in the left margin.

Ionization Energy. The ionization energy for arsenic (the least required energy to release a single electron from the atom in it's ground state in the gas phase) is stated in the following table:

1st Ionization Energy
944.46 kJ mol-1
2nd Ionization Energy
1797.82 kJ mol-1
3rd Ionization Energy
2735.48 kJ mol-1

Conductivity. As to arsenic's electrical and thermal conductivity, the electrical conductivity measured as to electrical resistivity @ 20 ºC is 33.3 μΩcm and its electronegativities (or its ability to draw electrons relative to other elements) is 2.18. The thermal conductivity of arsenic is 50 W m-1 K-1.

Thermal Properties. The melting point and boiling point for arsenic are stated below. The following chart sets forth the heat of fusion, heat of vaporization and heat of atomization.

Heat of Fusion
27.7 kJ mol-1
Heat of Vaporization
31.9 kJ mol-1
Heat of Atomization
301.42 kJ mol-1

 
Formula Atomic Number Molecular Weight Electronegativity (Pauling) Density Melting Point
Boiling Point
Vanderwaals radius
Ionic radius Energy of first ionization
As 33 74.9216 g.mol -1 2.0 5.7 g.cm-3 at 20 °C 814 °C 615 °C 185.pm 0.222 nm (-2) ; 0.047 (+5) ; 0.058 (+3) 944.46 7 kJ.mol-1

PRODUCT CATALOG UK Operations Submicron & Nanopowder Tolling Ultra High Purity Sputtering Target Crystal Growth Rod, Plate, Powder, etc. Foil
 
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Recent Research & Development for Arsenic

  • Arsenic attenuation by oxidized aquifer sediments in Bangladesh.
    Sci Total Environ. 2007 Jan 22; [Epub ahead of print]

  • Molecular mechanisms of antimony resistance in Leishmania.
    J Med Microbiol. 2007 Feb;56(Pt 2):143-53.

  • Chronic arsenic poisoning: a global health issue - a report of multiple primary cancers.
    J Cutan Pathol. 2007 Feb;34(2):203-6.

  • Characteristics of arsenic adsorption to sorghum biomass.
    J Hazard Mater. 2006 Nov 1; [Epub ahead of print]

  • Use of handheld X-ray fluorescence spectrometry units for identification of arsenic in treated wood.
    Environ Pollut. 2007 Jan 19; [Epub ahead of print]

  • Prevention of aneuploidy by S-adenosyl-methionine in human cells treated with sodium arsenite.
    Mutat Res. 2006 Dec 27; [Epub ahead of print]

  • Arsenic bioaccessibility and speciation in clams and seaweed from a contaminated marine environment.
    Mar Pollut Bull. 2007 Jan 20; [Epub ahead of print]

  • Effects of the plant flavonoids silymarin and quercetin on arsenite-induced oxidative stress in CHO-K1 cells.
    Food Chem Toxicol. 2006 Dec 13; [Epub ahead of print]

  • Effect of arsenic on photosynthesis, growth and yield of five widely cultivated rice (Oryza sativa L.) varieties in Bangladesh.
    Chemosphere. 2007 Jan 18; [Epub ahead of print]

  • Arsenic recovery from water containing arsenite and arsenate ions by hydrothermal mineralization.
    J Hazard Mater. 2006 Dec 15; [Epub ahead of print]

 

 

 

 

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