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Cadmium

 

Cadmium information, including Technical Data, Safety Data and its properties, research, applications and other useful facts are discussed below. Scientific facts such as the atomic structure, ionization energy, abundance on Earth, conductivity and thermal properties are included.

Cadmium is a component of some of the lowest melting alloys; it is used in bearing alloys with low coefficients of friction and great resistance to fatigue. Cadmium is used extensively in electroplating, which accounts for about 60% of its use. It is also used in many types of solder, for standard E.M.F. cells, for nickel-cadmium batteries, and as a barrier to control nuclear fission. Cadmium compounds are used in black and white television phosphors and in blue and green phosphors for color television tubes and CRT monitors. Cadmium in glass and ceramic glazes creates a distinctive cadmium yellow. It forms a number of compounds, of which the sulfate is most common; the sulfide is used as a yellow pigment. Cadmium is similar to carbon in that it has a capacity to form stable covalently bonded molecular networks. Cadmium is available as compounds with purities from 99% to 99.9999% (ACS grade to ultra-high purity).  Cadmium is also used in various metal alloys (See AE Alloys).

Cadmium facts, including appearance, CAS #, and molecular formula and safety data, research and properties are

 

  Hydrogen                                 Helium
  Lithium Beryllium                     Boron Carbon Nitrogen Oxygen Fluorine Neon
  Sodium Magnesium                     Aluminum Silicon Phosphorus Sulfur Chlorine Argon
  Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Hydrogen Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton
  Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon
  Cesium Barium Cerium Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury Thallium Lead Bismuth Polonium Astatine Radon
                                     
      Cerium Praseodymium Neodymium Promethium Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium    
      Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawerencium    


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available for many specific states, forms and shapes on the product pages listed to the left. Elemental or metallic forms include pellets, rod, wire and granules for evaporation source material purposes. Nanoparticles and nanopowders provide ultra high surface area which nanotechnology research and recent experiments demonstrate function to create new and unique properties and benefits.

Oxides are available in forms including powders and dense pellets for such uses as optical coating and thin film applications. Oxides tend to be insoluble. Fluorides are another insoluble form for uses in which oxygen is undesirable such as metallurgy, chemical and physical vapor deposition and in some optical coatings. Cadmium is available in soluble forms including chlorides, nitrates and acetates. These compounds are also manufactured as solutions at specified stoichiometries.

Cadmium is a Block D, Group 12, Period 5 element. The electronic configuration is [Kr] 4d10 5s2. In its elemental form cadmium's CAS number is 7440-43-9. The cadmium atom has a radius of 148.9.pm and it's Van der Waals radius is 158.pm.

All elemental metals, compounds and solutions may be synthesized in ultra high purity (e.g. 99.999%) for laboratory standards, advanced electronic, metallurgy and optical materials and other high technology advantages. Information is provided for stable (non-radioactive) isotopes. Organo-Metallic Cadmium compounds are soluble in organic or non-aqueous solvents. See Analytical Services for information on available certified chemical and physical analysis techniques including MS-ICP, X-Ray Diffraction, PSD and Surface Area (BET) analysis.

Cadmium was first discovered by Fredrich Stromeyer in 1817.

French Cadmium German Cadmium Italian Cadmio Portuguese Cádmio Spanish Cadmio Swedish Kadmium <

Abundance. The following table shows the abundance of cadmium and each of its naturally occurring isotopes on Earth along with the atomic mass for each isotope.

Isotope
Atomic Mass
% Abundance on Earth
Cd-106
105.906458
1.25
Cd-108
107.904183
0.89
Cd-110
109.903006
12.49
Cd-111
110.904182
12.80
Cd-112
111.902757
24.13
Cd-113
112.904401
12.22
Cd-114
113.903358
28.73
Cd-116
115.904755
7.49

Safety Data. The safety data for cadmium metal, nanoparticles and its compounds can vary widely depending on the form. For potential hazard information, toxicity, and road, sea and air transportation limitations, such as DOT Hazard Class, DOT Number, EU Number, NFPA Health rating and RTECS Class, please see the specific material or compound referenced in the left margin.

Ionization Energy. The ionization energy for cadmium (the least required energy to release a single electron from the atom in it's ground state in the gas phase) is stated in the following table:

1st Ionization Energy
867.78 kJ mol-1
2nd Ionization Energy
1631.42 kJ mol-1
3rd Ionization Energy
3616.30 kJ mol-1

Conductivity. As to cadmium's electrical and thermal conductivity, the electrical conductivity measured as to electrical resistivity @ 20 ºC is 6.83 μΩcm and its electronegativities (or its ability to draw electrons relative to other elements) is 1.69. The thermal conductivity of cadmium is 96.8 W m-1 K-1.

Thermal Properties. The melting point and boiling point for cadmium are stated below. The following chart sets forth the heat of fusion, heat of vaporization and heat of atomization.

Heat of Fusion
6.11 kJ mol-1
Heat of Vaporization
100 kJ mol-1
Heat of Atomization
112.05 kJ mol-1

 
Formula Atomic Number Molecular Weight Electronegativity (Pauling) Density Melting Point
Boiling Point
Vanderwaals radius
Ionic radius Energy of first ionization
Cd 48 112.4 g.mol -1 1.7 8.7 g.cm-3 at 20 °C 321 °C 767 °C 158.pm 0.097 nm (+2) 867.78 kJ.mol-1

PRODUCT CATALOG UK Operations Submicron & Nanopowder Tolling Ultra High Purity Sputtering Target Crystal Growth Rod, Plate, Powder, etc. Foil
 
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Recent Research & Development for Cadmium

  • Exploring potential dietary contributions including traditional seafood and other determinants of urinary cadmium levels among indigenous women of a Torres Strait Island (Australia).
    J Expo Sci Environ Epidemiol. 2007 Jan 24; [Epub ahead of print]

  • Cadmium-responsive element of the human heme oxygenase-1 gene mediates heat shock factor 1-dependent transcriptional activation.
    J Biol Chem. 2007 Jan 23; [Epub ahead of print]

  • Subcellular localization of cadmium in roots and leaves of Arabidopsis thaliana.
    New Phytol. 2007;173(3):495-508.

  • [The influence of cadmium and potassium on the level of cytogenetic effects induced by thallium-232 in Allium cepa root meristem]
    Tsitol Genet. 2006 Nov-Dec;40(6):50-8. Ukrainian.

  • Anion and cation leaching or desorption from activated carbons from municipal sludge and poultry manure as affected by pH.
    Water Environ Res. 2006 Nov;78(12):2324-9.

  • Metal Fractionation Study on Bed Sediments of Lake Nainital, Uttaranchal, India.
    Environ Monit Assess. 2007 Jan 23; [Epub ahead of print]

  • Hydroponic screening for metal resistance and accumulation of cadmium and zinc in twenty clones of willows and poplars.
    Environ Pollut. 2007 Jan 19; [Epub ahead of print]

  • Subcellular distribution of Cd in the aquatic oligochaete Tubifex tubifex, implications for trophic availability and toxicity.
    Environ Pollut. 2007 Jan 17; [Epub ahead of print]

  • Reversible alterations in epithelial cell turnover in digestive gland of winkles (Littorina littorea) exposed to cadmium and their implications for biomarker measurements.
    Aquat Toxicol. 2006 Dec 17; [Epub ahead of print]

  • Use of the juvenile clam, Mercenaria mercenaria, as a sensitive indicator of aqueous and sediment toxicity.
    Ecotoxicol Environ Saf. 2007 Jan 18; [Epub ahead of print]

 

 

 

 

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