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Germanium Telluride (By Crystallization)
Germanium
Germanium information, including Technical Data, Safety Data and its properties, research, applications and other useful facts are discussed below. Scientific facts such as the atomic structure, ionization energy, abundance on Earth, conductivity and thermal properties are included.

Germanium is a very important semiconductor. Zone-refining techniques have led to production of crystalline germanium for semiconductor use with extremely high purities. When germanium is doped with arsenic, gallium, or other elements, it is used as a transistor element in thousands of electronic applications. The most common use of germanium is as a semiconductor. Germanium is also finding many other applications including use as an alloying agent, as a phosphor in fluorescent lamps, and as a catalyst. Germanium and germanium oxide are transparent to the infrared and are used in infrared spectroscopes and other optical equipment, including extremely sensitive infrared detectors The high refractive index and dispersion properties of its oxide's have made germanium useful as a component of wide-angle camera lenses and microscope objectives. The field of organo-germanium chemistry is becoming increasingly important. Germanium is available as metal and compounds with purities from 99% to 99.9999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder.

Germanium facts, including appearance, CAS #, and molecular formula and safety data, research and properties are

 

  Hydrogen                                 Helium
  Lithium Beryllium                     Boron Carbon Nitrogen Oxygen Fluorine Neon
  Sodium Magnesium                     Aluminum Silicon Phosphorus Sulfur Chlorine Argon
  Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Hydrogen Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton
  Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon
  Cesium Barium Cerium Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury Thallium Lead Bismuth Polonium Astatine Radon
                                     
      Cerium Praseodymium Neodymium Promethium Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium    
      Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawerencium    


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available for many specific states, forms and shapes on the product pages listed to the left. Elemental or metallic forms include pellets, rod, wire and granules for evaporation source material purposes. Nanoparticles and nanopowders provide ultra high surface area which nanotechnology research and recent experiments demonstrate function to create new and unique properties and benefits.

Oxides are available in forms including powders and dense pellets for such uses as optical coating and thin film applications. Oxides tend to be insoluble. Fluorides are another insoluble form for uses in which oxygen is undesirable such as metallurgy, chemical and physical vapor deposition and in some optical coatings. Germanium is available in soluble forms including chlorides, nitrates and acetates. These compounds are also manufactured as solutions at specified stoichiometries.

Germanium is a Block P, Group 14, Period 4 element. The electronic configuration is [Ar] 3d10 4s2 4p2. In its elemental form germanium's CAS number is 7440-56-4. The germanium atom has a radius of 122.5.pm and it's Van der Waals radius is 200.pm.

All elemental metals, compounds and solutions may be synthesized in ultra high purity (e.g. 99.999%) for laboratory standards, advanced electronic, metallurgy and optical materials and other high technology advantages. Information is provided for stable (non-radioactive) isotopes. Organo-Metallic Germanium compounds are soluble in organic or non-aqueous solvents. See Analytical Services for information on available certified chemical and physical analysis techniques including MS-ICP, X-Ray Diffraction, PSD and Surface Area (BET) analysis.

Germanium was first discovered by Clemens Winkler in 1886.

French Germanium German Germanium Italian Germanio Portuguese Germânio Spanish Germanio Swedish Germanium

Abundance. The following table shows the abundance of germanium and each of its naturally occurring isotopes on Earth along with the atomic mass for each isotope.

Isotope
Atomic Mass
% Abundance on Earth
Ge-70
69.924250
21.23
Ge-72
71.922076
27.66
Ge-73
72.923459
7.73
Ge-74
73.921178
35.94
Ge-76
75.921403
7.44

Safety Data. The safety data for germanium metal, nanoparticles and its compounds can vary widely depending on the form. For potential hazard information, toxicity, and road, sea and air transportation limitations, such as DOT Hazard Class, DOT Number, EU Number, NFPA Health rating and RTECS Class, please see the specific material or compound referenced in the left margin.

Ionization Energy. The ionization energy for germanium (the least required energy to release a single electron from the atom in it's ground state in the gas phase) is stated in the following table:

1st Ionization Energy
762.18 kJ mol-1
2nd Ionization Energy
1537.47 kJ mol-1
3rd Ionization Energy
3302.15 kJ mol-1

Conductivity. As to germanium's electrical and thermal conductivity, the electrical conductivity measured as to electrical resistivity @ 20 ºC is 46000000 μΩcm and its electronegativities (or its ability to draw electrons relative to other elements) is 2.01. The thermal conductivity of germanium is 122.5 W m-1 K-1.

Thermal Properties. The melting point and boiling point for germanium are stated below. The following chart sets forth the heat of fusion, heat of vaporization and heat of atomization.

Heat of Fusion
34.7 kJ mol-1
Heat of Vaporization
327.6 kJ mol-1
Heat of Atomization
373.8 kJ mol-1

 
Formula Atomic Number Molecular Weight Electronegativity (Pauling) Density Melting Point
Boiling Point
Vanderwaals radius
Ionic radius Energy of first ionization
Ge 32 72.59 g.mol -1 1.8 5.3 g.cm-3 at 20 °C 937 °C 2830 °C 200.pm 0.093 nm (+2) ; 0.054 (+4) 762.18 kJ.mol-1

PRODUCT CATALOG UK Operations Submicron & Nanopowder Tolling Ultra High Purity Sputtering Target Crystal Growth Rod, Plate, Powder, etc. Foil
 
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Recent Research & Development for Germanium

  • Electronic Properties of Si and Ge Atoms Doped In Clusters: In(n)()Si(m)() and In(n)()Ge(m)().
    J Phys Chem A Mol Spectrosc Kinet Environ Gen Theory. 2007 Feb 1;111(4):573-7.

  • Self-Assembly and Phase Behavior of Germanium Oxide Nanoparticles in Basic Aqueous Solutions.
    Langmuir. 2007 Jan 23; [Epub ahead of print]

  • [Au(3)Ge(18)](5-)-A germanium-Germanium Cluster with Remarkable Au-Au Interactions.
    Angew Chem Int Ed Engl. 2007 Jan 18; [Epub ahead of print] No abstract available.

  • Monolayers at solid-solid interfaces probed with infrared spectroscopy.
    Anal Bioanal Chem. 2007 Jan 10; [Epub ahead of print]

  • Biochemical Interaction Analysis on ATR Devices: A Wet Chemistry Approach for Surface Functionalization.
    Langmuir. 2007 Jan 16;23(2):949-955.

  • Density functional theory study of twelve-atom germanium clusters: conflict between the Wade-Mingos rules and optimum vertex degrees.
    Dalton Trans. 2007 Jan 21;(3):364-72. Epub 2006 Dec 8.

  • Crystallography and surface faceting of germanium nanowires.
    Small. 2005 Jul;1(7):717-21. No abstract available.

  • Temperature-dependent growth of germanium oxide and silicon oxide based nanostructures, aligned silicon oxide nanowire assemblies, and silicon oxide microtubes.
    Small. 2005 Apr;1(4):429-38.

  • {Ge(10)Si[Si(SiMe(3))(3)](4)(SiMe(3))(2)Me}(-): A Ge(10)Si framework reveals a structural transition onto elemental germanium.
    Chem Commun (Camb). 2007 Jan 14;(2):192-4. Epub 2006 Oct 24.

  • DETERMINATION OF CONVERSION FACTORS FROM AIR KERMA TO OPERATIONAL DOSE EQUIVALENT QUANTITIES FOR LOW-ENERGY X-RAY SPECTRA.
    Radiat Prot Dosimetry. 2006 Dec 16; [Epub ahead of print]

 

 

 

 

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