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Niobium
Niobium information, including safety data and its properties, research, applications and other useful facts are discussed below. Scientific facts such as the atomic structure, ionization energy, abundance on Earth, conductivity and thermal properties are included.

Niobium is the basis for various barium titanate compositions used as dielectric coatings in telecommunications and small advanced electronics, such as cell phones, pagers and laptop computers. Niobium is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. Niobium has medical research applications. It is alloyed to produce arc-welding rods and in corrosion-resistant steel.

Niobium facts, including appearance, CAS #, and molecular formula and safety data, research and properties are

 

  Hydrogen                                 Helium
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  Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Hydrogen Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton
  Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon
  Cesium Barium Cerium Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury Thallium Lead Bismuth Polonium Astatine Radon
                                     
      Cerium Praseodymium Neodymium Promethium Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium    
      Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawerencium    


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available for many specific states, forms and shapes on the product pages listed to the left. Elemental or metallic forms include pellets, rod, wire and granules for evaporation source material purposes. Nanoparticles and nanopowders provide ultra high surface area which nanotechnology research and recent experiments demonstrate function to create new and unique properties and benefits.

Oxides are available in forms including powders and dense pellets for such uses as optical coating and thin film applications. Oxides tend to be insoluble. Fluorides are another insoluble form for uses in which oxygen is undesirable such as metallurgy, chemical and physical vapor deposition and in some optical coatings. Niobium is available in soluble forms including chlorides, nitrates and acetates. These compounds are also manufactured as solutions at specified stoichiometries.

Niobium is a Block D, Group 5, Period 5 element. The electronic configuration is [Kr] 4d4 5s1. In its elemental form niobium's CAS number is 7440-03-1. The niobium atom has a radius of 142.9.pm and it's Van der Waals radius is 200.pm.

All elemental metals, compounds and solutions may be synthesized in ultra high purity (e.g. 99.999%) for laboratory standards, advanced electronic, metallurgy and optical materials and other high technology advantages. Information is provided for stable (non-radioactive) isotopes. Organo-Metallic Niobium compounds are soluble in organic or non-aqueous solvents. See Analytical Services for information on available certified chemical and physical analysis techniques including MS-ICP, X-Ray Diffraction, PSD and Surface Area (BET) analysis.

Niobium was first discovered by Charles Hatchett in 1801.

French niobium German Niob Italian niobio Portuguese Nióbio Spanish niobio Swedish Niob

Abundance. The following table shows the abundance of niobium and each of its naturally occurring isotopes on Earth along with the atomic mass for each isotope.

Isotope
Atomic Mass
% Abundance on Earth
Nb-93
92.906378
100

Safety Data. The safety data for niobium metal, nanoparticles and its compounds can vary widely depending on the form. For potential hazard information, toxicity, and road, sea and air transportation limitations, such as DOT Hazard Class, DOT Number, EU Number, NFPA Health rating and RTECS Class, please see the specific material or compound referenced in the left margin.

Ionization Energy. The ionization energy for niobium (the least required energy to release a single electron from the atom in it's ground state in the gas phase) is stated in the following table:

1st Ionization Energy
652.13 kJ mol-1
2nd Ionization Energy
1381.68 kJ mol-1
3rd Ionization Energy
2416.01 kJ mol-1

Conductivity. As to niobium's electrical and thermal conductivity, the electrical conductivity measured as to electrical resistivity @ 20 ºC is 12.5 μΩcm and its electronegativities (or its ability to draw electrons relative to other elements) is 1.6. The thermal conductivity of niobium is 53.7 W m-1 K-1.

Thermal Properties. The melting point and boiling point for niobium are stated below. The following chart sets forth the heat of fusion, heat of vaporization and heat of atomization.

Heat of Fusion
27.2 kJ mol-1
Heat of Vaporization
680.19 kJ mol-1
Heat of Atomization
722.819 kJ mol-1

 
Formula Atomic Number Molecular Weight Electronegativity (Pauling) Density Melting Point
Boiling Point
Vanderwaals radius
Ionic radius Energy of first ionization
Nb 41 92.91 g.mol -1 unknown 8.4 g.cm-3 at 20 °C 2410 °C 5100 °C 200.pm 0.070 nm (+5) ; 0.069 (+4) 652.13 kJ.mol-1

PRODUCT CATALOG UK Operations Submicron & Nanopowder Tolling Ultra High Purity Sputtering Target Crystal Growth Rod, Plate, Powder, etc. Foil
 
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Recent Research & Development for Niobium

  • Stoichiometry and valence measurements of niobium oxides using electron energy-loss spectroscopy.
    J Microsc. 2006 Dec;224(3):233-241.

  • Two organically templated niobium and zinconiobium fluorophosphates: low temperature hydrothermal syntheses of NbOF(PO4)2(C2H10N2)2 and Zn3(NbOF)(PO4)4(C2H10N2)2.
    Inorg Chem. 2007 Jan 8;46(1):231-7.

  • Vertically aligned carbon-nanotube arrays showing schottky behavior at room temperature.
    Small. 2005 May;1(5):553-9.

  • Phase transformations in bulk nanostructured potassium niobiosilicate glasses.
    J Phys Chem B Condens Matter Mater Surf Interfaces Biophys. 2006 Dec 28;110(51):25740-5.

  • Activation of atmospheric nitrogen and azobenzene N=N bond cleavage by a transient Nb(III) complex.
    Inorg Chem. 2006 Dec 25;45(26):10712-21.

  • Enantioselective Desymmetrization of meso Epoxides with Anilines Catalyzed by a Niobium Complex of a Chiral Multidentate Binol Derivative.
    Angew Chem Int Ed Engl. 2006 Dec 18; [Epub ahead of print] No abstract available.

  • Core structure of eremophilanes and bakkanes through niobium catalyzed Diels-Alder reaction: synthesis of (+/-)-bakkenolide A.
    J Org Chem. 2006 Dec 22;71(26):9880-3.

  • C-H bond activation of arenes by a transient eta2-cyclopropene niobium complex.
    J Am Chem Soc. 2006 Dec 20;128(50):15962-3. No abstract available.

  • On the performance of Fe and Fe,F doped Ti-Pt/PbO(2) electrodes in the electrooxidation of the Blue Reactive 19 dye in simulated textile wastewater.
    Chemosphere. 2007 Feb;66(11):2035-43. Epub 2006 Nov 30.

  • Formation and distribution of neutral vanadium, niobium, and tantalum oxide clusters: single photon ionization at 26.5 eV.
    J Chem Phys. 2006 Oct 28;125(16):164318.

 

 

 

 

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