Nickel-Cobalt Diselenide 3D Mesoporous Nanosheet Networks Supported on Ni Foam: An All-pH Highly Efficient Integrated Electrocatalyst for Hydrogen Evolution.

Title Nickel-Cobalt Diselenide 3D Mesoporous Nanosheet Networks Supported on Ni Foam: An All-pH Highly Efficient Integrated Electrocatalyst for Hydrogen Evolution.
Authors B. Liu; Y.F. Zhao; H.Q. Peng; Z.Y. Zhang; C.K. Sit; M.F. Yuen; T.R. Zhang; C.S. Lee; W.J. Zhang
Journal Adv Mater
DOI 10.1002/adma.201606521
Abstract

Novel 3D Ni1-x Cox Se2 mesoporous nanosheet networks with tunable stoichiometry are successfully synthesized on Ni foam (Ni1-x Cox Se2 MNSN/NF with x ranging from 0 to 0.35). The collective effects of special morphological design and electronic structure engineering enable the integrated electrocatalyst to have very high activity for hydrogen evolution reaction (HER) and excellent stability in a wide pH range. Ni0.89 Co0.11 Se2 MNSN/NF is revealed to exhibit an overpotential (?10 ) of 85 mV at -10 mA cm(-2) in alkaline medium (pH 14) and ?10 of 52 mV in acidic solution (pH 0), which are the best among all selenide-based electrocatalysts reported thus far. In particular, it is shown for the first time that the catalyst can work efficiently in neutral solution (pH 7) with a record ?10 of 82 mV for all noble metal-free electrocatalysts ever reported. Based on theoretical calculations, it is further verified that the advanced all-pH HER activity of Ni0.89 Co0.11 Se2 is originated from the enhanced adsorption of both H(+) and H2 O induced by the substitutional doping of cobalt at an optimal level. It is believed that the present work provides a valuable route for the design and synthesis of inexpensive and efficient all-pH HER electrocatalysts.

Citation B. Liu; Y.F. Zhao; H.Q. Peng; Z.Y. Zhang; C.K. Sit; M.F. Yuen; T.R. Zhang; C.S. Lee; W.J. Zhang.Nickel-Cobalt Diselenide 3D Mesoporous Nanosheet Networks Supported on Ni Foam: An All-pH Highly Efficient Integrated Electrocatalyst for Hydrogen Evolution.. Adv Mater Weinheim. 2017;29(19). doi:10.1002/adma.201606521

Related Elements

Cobalt

See more Cobalt products. Cobalt (atomic symbol: Co, atomic number: 27) is a Block D, Group 9, Period 4 element with an atomic weight of 58.933195. Cobalt Bohr ModelThe number of electrons in each of cobalt's shells is 2, 8, 15, 2 and its electron configuration is [Ar]3d7 4s2. The cobalt atom has a radius of 125 pm and a Van der Waals radius of 192 pm. Cobalt was first discovered by George Brandt in 1732. In its elemental form, cobalt has a lustrous gray appearance. Cobalt is found in cobaltite, erythrite, glaucodot and skutterudite ores. Elemental CobaltCobalt produces brilliant blue pigments which have been used since ancient times to color paint and glass. Cobalt is a ferromagnetic metal and is used primarily in the production of magnetic and high-strength superalloys. Co-60, a commercially important radioisotope, is useful as a radioactive tracer and gamma ray source. The origin of the word Cobalt comes from the German word "Kobalt" or "Kobold," which translates as "goblin," "elf" or "evil spirit.

Nickel

See more Nickel products. Nickel (atomic symbol: Ni, atomic number: 28) is a Block D, Group 4, Period 4 element with an atomic weight of 58.6934. Nickel Bohr ModelThe number of electrons in each of nickel's shells is [2, 8, 16, 2] and its electron configuration is [Ar]3d8 4s2. Nickel was first discovered by Alex Constedt in 1751. The nickel atom has a radius of 124 pm and a Van der Waals radius of 184 pm. In its elemental form, nickel has a lustrous metallic silver appearance. Nickel is a hard and ductile transition metal that is considered corrosion-resistant because of its slow rate of oxidation. Elemental NickelIt is one of four elements that are ferromagnetic and is used in the production of various type of magnets for commercial use. Nickel is sometimes found free in nature but is more commonly found in ores. The bulk of mined nickel comes from laterite and magmatic sulfide ores. The name originates from the German word kupfernickel, which means "false copper" from the illusory copper color of the ore.

Selenium

Selenium Bohr ModelSee more Selenium products. Selenium (atomic symbol: Se, atomic number: 34) is a Block P, Group 16, Period 4 element with an atomic radius of 78.96. The number of electrons in each of Selenium's shells is 2, 8, 18, 6 and its electron configuration is [Ar] 3d10 4s2 4p4. The selenium atom has a radius of 120 pm and a Van der Waals radius of 190 pm. Selenium is a non-metal with several allotropes: a black, vitreous form with an irregular crystal structure three red-colored forms with monoclinic crystal structures and a gray form with a hexagonal crystal structure, the most stable and dense form of the element. Elemental SeleniumOne of the most common uses for selenium is in glass production the red tint that it lends to glass neutralizes green or yellow tints from impurities in the glass materials. Selenium was discovered and first isolated by Jöns Jakob Berzelius and Johann Gottlieb Gahn in 1817. The origin of the name Selenium comes from the Greek word "Selênê," meaning moon.

Related Forms & Applications