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Osmium
Osmium information, including safety data and its properties, research, applications and other useful facts are discussed below. Scientific facts such as the atomic structure, ionization energy, abundance on Earth, conductivity and thermal properties are included.

Osmium has the highest melting point and the lowest vapor pressure of any of the platinum group of metals. Osmium tetroxide has recently been used to detect fingerprints and as an aid to stain fatty tissue for microscope slides. The metal is almost entirely used to produce very hard alloys with other metals of the platinum group. Osmium is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder.

Osmium facts, including appearance, CAS #, and molecular formula and safety data, research and properties are

 

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  Cesium Barium Cerium Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury Thallium Lead Bismuth Polonium Astatine Radon
                                     
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available for many specific states, forms and shapes on the product pages listed to the left. Elemental or metallic forms include pellets, rod, wire and granules for evaporation source material purposes. Nanoparticles and nanopowders provide ultra high surface area which nanotechnology research and recent experiments demonstrate function to create new and unique properties and benefits.

Oxides are available in forms including powders and dense pellets for such uses as optical coating and thin film applications. Oxides tend to be insoluble. Fluorides are another insoluble form for uses in which oxygen is undesirable such as metallurgy, chemical and physical vapor deposition and in some optical coatings. Osmium is available in soluble forms including chlorides, nitrates and acetates. These compounds are also manufactured as solutions at specified stoichiometries.

Osmium is a Block D, Group 8, Period 6 element. The electronic configuration is [Xe] 4f14 5d6 6s2. In its elemental form osmium's CAS number is 7440-04-2. The osmium atom has a radius of 133.8.pm and it's Van der Waals radius is 200.pm.

All elemental metals, compounds and solutions may be synthesized in ultra high purity (e.g. 99.999%) for laboratory standards, advanced electronic, metallurgy and optical materials and other high technology advantages. Information is provided for stable (non-radioactive) isotopes. Organo-Metallic Osmium compounds are soluble in organic or non-aqueous solvents. See Analytical Services for information on available certified chemical and physical analysis techniques including MS-ICP, X-Ray Diffraction, PSD and Surface Area (BET) analysis.

Osmium was first discovered by Smithson Tennant in 1803.

French osmium German Osmium Italian osmio Portuguese Ósmio Spanish osmio Swedish Osmium

Abundance. The following table shows the abundance of hafnium and each of its naturally occurring isotopes on Earth along with the atomic mass for each isotope.

Isotope
Atomic Mass
% Abundance on Earth
Os-184
183.952491
0.02
Os-186
185.953838
1.58
Os-187
186.955748
1.6
Os-188
187.955836
13.3
Os-189
188.958145
16.1
Os-190
189.958445
26.4
Os-192
191.961479
41.0

Safety Data. The safety data for osmium metal, nanoparticles and its compounds can vary widely depending on the form. For potential hazard information, toxicity, and road, sea and air transportation limitations, such as DOT Hazard Class, DOT Number, EU Number, NFPA Health rating and RTECS Class, please see the specific material or compound referenced in the left margin.

Ionization Energy. The ionization energy for osmium (the least required energy to release a single electron from the atom in it's ground state in the gas phase) is stated in the following table:

1st Ionization Energy
814.17 kJ mol-1
2nd Ionization Energy
- kJ mol-1
3rd Ionization Energy
- kJ mol-1

Conductivity. As to osmium's electrical and thermal conductivity, the electrical conductivity measured as to electrical resistivity @ 20 ºC is 9.5 μΩcm and its electronegativities (or its ability to draw electrons relative to other elements) is 2.2. The thermal conductivity of osmium is 87.6 W m-1 K-1.

Thermal Properties. The melting point and boiling point for osmium are stated below. The following chart sets forth the heat of fusion, heat of vaporization and heat of atomization.

Heat of Fusion
29.3 kJ mol-1
Heat of Vaporization
738.06 kJ mol-1
Heat of Atomization
791 kJ mol-1

 
Formula Atomic Number Molecular Weight Electronegativity (Pauling) Density Melting Point
Boiling Point
Vanderwaals radius
Ionic radius Energy of first ionization
Os 76 190.2 g.mol -1 2.2 22.5 g.cm-3 at 20 °C 3045 °C 5027 °C 200.pm 0.067 nm (+4) 814.17 kJ.mol-1

PRODUCT CATALOG UK Operations Submicron & Nanopowder Tolling Ultra High Purity Sputtering Target Crystal Growth Rod, Plate, Powder, etc. Foil
 
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Recent Research & Development for Osmium

  • Ultrafast and Ultraslow Oxygen Atom Transfer Reactions between Late Metal Centers.
    J Am Chem Soc. 2007 Jan 24;129(3):588-600.

  • Highly siderophile element constraints on accretion and differentiation of the Earth-Moon system.
    Science. 2007 Jan 12;315(5809):217-9.

  • Characterization of a glucose sensor prepared by electropolymerization of pyrroles containing a tris-bipyridine osmium complex.
    Anal Sci. 2007 Jan;23(1):59-63.

  • Osmium(II) and Ruthenium(II) Arene Maltolato Complexes: Rapid Hydrolysis and Nucleobase Binding.
    Chemistry. 2007 Jan 2; [Epub ahead of print]

  • A density functional theory study of the electronic properties of Os(II) and Os(III) complexes immobilized on Au(111).
    Inorg Chem. 2007 Jan 8;46(1):117-24.

  • Enhanced visualization of microbial biofilms by staining and environmental scanning electron microscopy.
    J Microbiol Methods. 2006 Dec 28; [Epub ahead of print]

  • Methylcytosine-selective fluorescence quenching by osmium complexation.
    Bioorg Med Chem. 2007 Feb 15;15(4):1615-21. Epub 2006 Dec 15.

  • Lysosomal accumulation of SCMAS (subunit c of mitochondrial ATP synthase) in neurons of the mouse model of mucopolysaccharidosis III B.
    Mol Genet Metab. 2006 Dec 19; [Epub ahead of print]

  • Copper- and iron-rich matrices in hepatocellular lipofuscin particles of a young male patient: diagnostic ultrastructures for Wilson disease.
    Ultrastruct Pathol. 2006 Nov-Dec;30(6):409-14.

  • Development of a carbon nanotube paste electrode osmium polymer-mediated biosensor for determination of glucose in alcoholic beverages.
    Biosens Bioelectron. 2006 Dec 15; [Epub ahead of print]

 

 

 

 

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