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Praseodymium
Praseodymium information, including safety data and its properties, research, applications and other useful facts are discussed below. Scientific facts such as the atomic structure, ionization energy, abundance on Earth, conductivity and thermal properties are included.

Praseodymium resembles the typical trivalent rare earths, however, it will exhibit a +4 state when stabilized in a zirconia host. Praseodymium is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. The element is found in most all light rare earth derivatives. It is highly valued in glass and ceramic production as a bright yellow pigment because of its optimum reflectance at 560 nm. Much research is being done on its optical properties for use in amplification of telecommunication systems, including as a doping agent in fluoride fibers. Praseodymium doped zirconia is a potential cathode for low temperature Solid Oxide Fuel Cell applications. It is also used in the scintillator for medical CAT scans.

Praseodymium facts, including appearance, CAS #, and molecular formula and safety data, research and properties are

 

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      Cerium Praseodymium Neodymium Promethium Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium    
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available for many specific states, forms and shapes on the product pages listed to the left. Elemental or metallic forms include pellets, rod, wire and granules for evaporation source material purposes. Nanoparticles and nanopowders provide ultra high surface area which nanotechnology research and recent experiments demonstrate function to create new and unique properties and benefits.

Oxides are available in forms including powders and dense pellets for such uses as optical coating and thin film applications. Oxides tend to be insoluble. Fluorides are another insoluble form for uses in which oxygen is undesirable such as metallurgy, chemical and physical vapor deposition and in some optical coatings. Praseodymium is available in soluble forms including chlorides, nitrates and acetates. These compounds are also manufactured as solutions at specified stoichiometries.

Praseodymium is a Block F, Group 3, Period 6 element. The electronic configuration is [Xe]4f36s2. In its elemental form praseodymium's CAS number is 7440-10-0. The praseodymium atom has a radius of 182.pm and it's Van der Waals radius is is unknown.

All elemental metals, compounds and solutions may be synthesized in ultra high purity (e.g. 99.999%) for laboratory standards, advanced electronic, metallurgy and optical materials and other high technology advantages. Information is provided for stable (non-radioactive) isotopes. Organo-Metallic Praseodymium compounds are soluble in organic or non-aqueous solvents. See Analytical Services for information on available certified chemical and physical analysis techniques including MS-ICP, X-Ray Diffraction, PSD and Surface Area (BET) analysis.

Praseodymium was first discovered by von Welsbach in 1885.

Frenchpraséodyme German Praseodym Italianpraseodimio Portuguese Prosedímio Spanishpraseodimio Swedish Praseodym

Praseodymium Abundance. The following table shows the abundance of Praseodymium and each of its naturally occurring isotopes on Earth along with the atomic mass for each isotope.

Isotope
Atomic Mass
% Abundance on Earth
Pr-141
140.908
100

Praseodymium Safety Data. The safety data for Praseodymium metal, nanoparticles and its compounds can vary widely depending on the form. For potential hazard information, toxicity, and road, sea and air transportation limitations, such as DOT Hazard Class, DOT Number, EU Number, NFPA Health rating and RTECS Class, please see the specific material or compound referenced in the left margin.

Ionization Energy. The ionization energy for Praseodymium (the least required energy to release a single electron from the atom in it's ground state in the gas phase) is stated in the following table:

1st Ionization Energy
527.20 kJ mol-1
2nd Ionization Energy
1017.93 kJ mol-1
3rd Ionization Energy
2086.41 kJ mol-1

Conductivity. As to Praseodymium's electrical and thermal conductivity, the electrical conductivity measured in terms of electrical resistivity @ 20 ºC is 68 µOcm and its electronegativities (or its ability to draw electrons relative to other elements) is 1.13. The thermal conductivity of Praseodymium is 12.5 W m-1 K-1.

Thermal Properties of Praseodymium. The melting point and boiling point for Praseodymium are stated below. The following chart sets forth the heat of fusion, heat of vaporization and heat of atomization.

Heat of Fusion
11.3 kJ mol-1
Heat of Vaporization
357 kJ mol-1
Heat of Atomization
356.69 kJ mol-1



 
Formula Atomic Number Molecular Weight Electronegativity (Pauling) Density Melting Point
Boiling Point
Vanderwaals radius
Ionic radius Energy of first ionization
Pr 59 140.91 g.mol -1 1.1 6.8 g.cm-3 at 20 °C 931 °C 3512 °C unknown 0.101 nm (+3) 522 kJ.mol-1

PRODUCT CATALOG UK Operations Submicron & Nanopowder Tolling Ultra High Purity Sputtering Target Crystal Growth Rod, Plate, Powder, etc. Foil
 
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Recent Research & Development for Praseodymium

  • Modified rare earth semiconductor oxide as a new nucleotide probe.
    J Phys Chem B Condens Matter Mater Surf Interfaces Biophys. 2006 Dec 28;110(51):25633-7.

  • Studies on the sorption of praseodymium (III), holmium (III) and cobalt (II) from nitrate medium using TVEX-PHOR resin.
    J Hazard Mater. 2006 Sep 1; [Epub ahead of print]

  • Weaning pig performance and faecal microbiota with and without in-feed addition of rare earth elements.
    J Anim Physiol Anim Nutr (Berl). 2006 Oct;90(9-10):361-8.

  • Numerical analysis and experimental results of high-power Er/Pr:ZBLAN 2.7 microm fiber lasers with different pumping designs.
    Appl Opt. 2006 Sep 20;45(27):7118-25.

  • Synthesis, spectroscopic, thermal and antifungal studies on lanthanum(III) and praseodymium(III) derivatives of 1,1-diacetylferrocenyl hydrazones.
    Spectrochim Acta A Mol Biomol Spectrosc. 2006 Sep;65(1):139-42. Epub 2006 Jul 28.

  • Photophysical properties of praseodymium complexes with aromatic carboxylic acids: Double light conversion both in ultraviolet and visible region.
    Spectrochim Acta A Mol Biomol Spectrosc. 2006 Jun 2; [Epub ahead of print]

  • Self-assembly of PcOC8 and its sandwich lanthanide complex Pr(PcOC8)(2) with oligo(phenylene-ethynylene) molecules.
    J Phys Chem B Condens Matter Mater Surf Interfaces Biophys. 2005 Oct 27;109(42):19859-65.

  • Electronic and chemical properties of nanostructured cerium dioxide doped with praseodymium.
    J Phys Chem B Condens Matter Mater Surf Interfaces Biophys. 2005 Mar 31;109(12):5728-38.

  • Double fluorescence conversion in ultraviolet and visible region for some praseodymium complexes of aromatic carboxyates.
    J Fluoresc. 2006 Jul;16(4):495-500. Epub 2006 Jun 15.

  • Praseodymium hydroxide and oxide nanorods and Au/Pr6O11 nanorod catalysts for CO oxidation.
    J Phys Chem B Condens Matter Mater Surf Interfaces Biophys. 2006 Feb 2;110(4):1614-20.

 

 

 

 

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