American Elements
   



Products
Rhodium Chloride
Rhodium
Rhodium information, including Technical Data, Safety Data and its properties, research, applications and other useful facts are discussed below. Scientific facts such as the atomic structure, ionization energy, abundance on Earth, conductivity and thermal properties are included.

Rhodium is a member of the platinum group of metals. It has a higher melting point than platinum, but a lower density. It is alloyed with platinum and palladium in electrodes for spark plugs, advanced laboratory equipment and in thermocouples. Rhodium compounds also have catalytic uses in automotive catalytic converters. Rhodium is used as a plating metal in jewelry production to enhance the whiteness of white gold. Rhodium is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder.

Rhodium facts, including appearance, CAS #, and molecular formula and safety data, research and properties are

 

  Hydrogen                                 Helium
  Lithium Beryllium                     Boron Carbon Nitrogen Oxygen Fluorine Neon
  Sodium Magnesium                     Aluminum Silicon Phosphorus Sulfur Chlorine Argon
  Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Hydrogen Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton
  Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon
  Cesium Barium Cerium Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury Thallium Lead Bismuth Polonium Astatine Radon
                                     
      Cerium Praseodymium Neodymium Promethium Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium    
      Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawerencium    


(click on an element)
available for many specific states, forms and shapes on the product pages listed to the left. Elemental or metallic forms include pellets, rod, wire and granules for evaporation source material purposes. Nanoparticles and nanopowders provide ultra high surface area which nanotechnology research and recent experiments demonstrate function to create new and unique properties and benefits.

Oxides are available in forms including powders and dense pellets for such uses as optical coating and thin film applications. Oxides tend to be insoluble. Fluorides are another insoluble form for uses in which oxygen is undesirable such as metallurgy, chemical and physical vapor deposition and in some optical coatings. Rhodium is available in soluble forms including chlorides, nitrates and acetates. These compounds are also manufactured as solutions at specified stoichiometries.

Rhodium is a Block D, Group 9, Period 5 element. The electronic configuration is [Kr] 4d8 5s1. In its elemental form rhodium's CAS number is 7440-16-6. The rhodium atom has a radius of 134.5.pm and it's Van der Waals radius is 200.pm.

All elemental metals, compounds and solutions may be synthesized in ultra high purity (e.g. 99.999%) for laboratory standards, advanced electronic, metallurgy and optical materials and other high technology advantages. Information is provided for stable (non-radioactive) isotopes. Organo-Metallic Rhodium compounds are soluble in organic or non-aqueous solvents. See Analytical Services for information on available certified chemical and physical analysis techniques including MS-ICP, X-Ray Diffraction, PSD and Surface Area (BET) analysis.

Rhodium was first discovered by William Wollaston in 1803.

French Rhodium German Rhodium Italian Rodio Portuguese Ródio Spanish Rodio Swedish Rhodium

Abundance. The following table shows the abundance of rhodium and each of its naturally occurring isotopes on Earth along with the atomic mass for each isotope.

Isotope
Atomic Mass
% Abundance on Earth
Rh-103
102.905504
100

Safety Data. The safety data for rhodium metal, nanoparticles and its compounds can vary widely depending on the form. For potential hazard information, toxicity, and road, sea and air transportation limitations, such as DOT Hazard Class, DOT Number, EU Number, NFPA Health rating and RTECS Class, please see the specific material or compound referenced in the left margin.

Ionization Energy. The ionization energy for rhodium (the least required energy to release a single electron from the atom in it's ground state in the gas phase) is stated in the following table:

1st Ionization Energy
719.68 kJ mol-1
2nd Ionization Energy
1744.47 kJ mol-1
3rd Ionization Energy
2996.86 kJ mol-1

Conductivity. As to rhodium's electrical and thermal conductivity, the electrical conductivity measured as to electrical resistivity @ 20 șC is 4.51 μΩcm and its electronegativities (or its ability to draw electrons relative to other elements) is 2.28. The thermal conductivity of rhodium is 150 W m-1 K-1.

Thermal Properties. The melting point and boiling point for rhodium are stated below. The following chart sets forth the heat of fusion, heat of vaporization and heat of atomization.

Heat of Fusion
21.55 kJ mol-1
Heat of Vaporization
494.34 kJ mol-1
Heat of Atomization
555.59 kJ mol-1

 
Formula Atomic Number Molecular Weight Electronegativity (Pauling) Density Melting Point
Boiling Point
Vanderwaals radius
Ionic radius Energy of first ionization
Rh 45 102.91 g.mol -1 2.2 12.4 g.cm-3 at 20 °C 1970 °C 3727 °C 200.pm unknown 719.68 kJ.mol-1

PRODUCT CATALOG UK Operations Submicron & Nanopowder Tolling Ultra High Purity Sputtering Target Crystal Growth Rod, Plate, Powder, etc. Foil
 
© 2001-2007. American Elements is a U.S. Registered Trademark. All rights reserved.
This website and all pages, designs, concepts, logos, and color schemes herein are
the copyrighted proprietary rights and intellectual property of American Elements.

 

Recent Research & Development for Rhodium

  • Anomalous Reaction of Rh(2)(OAc)(4)-Generated Transient Carbonyl Ylides: Chemoselective Synthesis of Epoxy-Bridged Tetrahydropyranone, Oxepanone, Oxocinone, and Oxoninone Ring Systems.
    J Org Chem. 2007 Jan 23; [Epub ahead of print]

  • De Novo Synthesis of Troc-Protected Amines: Intermolecular Rhodium-Catalyzed C-H Amination with N-Tosyloxycarbamates.
    Org Lett. 2007 Jan 23; [Epub ahead of print]

  • An Unexpected Pathway for the Catalytic Oxidation of Methylidyne on Rh{111} as a Route to Syngas.
    J Am Chem Soc. 2007 Jan 23; [Epub ahead of print]

  • Initial clinical experience with contrast-enhanced digital breast tomosynthesis.
    Acad Radiol. 2007 Feb;14(2):229-38.

  • Reverse micelle synthesis of rhodium nanoparticles.
    J Colloid Interface Sci. 2006 Dec 28; [Epub ahead of print]

  • Synthesis of Potent Bicyclic Bisarylimidazole c-Jun N-Terminal Kinase Inhibitors by Catalytic C-H Bond Activation.
    J Am Chem Soc. 2007 Jan 24;129(3):490-1.

  • Hydrogen-Atom Transfer in Open-Shell Organometallic Chemistry: The Reactivity of Rh(II)(cod) and Ir(II)(cod) Radicals.
    Chemistry. 2007 Jan 12; [Epub ahead of print]

  • Rhodium(I)-Catalyzed Allenic Carbocyclization Reaction Affording delta- and epsilon-Lactams.
    Org Lett. 2007 Jan 18;9(2):347-9.

  • Separation preconcentration method for platinum and rhodium from environmental samples using a chelating resin.
    Ann Chim. 2006 Nov-Dec;96(11-12):707-14.

  • Rhodium diphosphite pincer complexes. Rare preferred in-plane olefin conformation in square-planar compounds.
    Dalton Trans. 2007 Jan 28;(4):407-9. Epub 2006 Dec 13.

 

 

 

 

American Elements Products can also be sourced at these sites:
 
 
 
electronics-ee.com