Synthesis of Scandium Terminal Hydride From H2 Activation by Scandium Terminal Imido Complex and Its Reactivity.

Title Synthesis of Scandium Terminal Hydride From H2 Activation by Scandium Terminal Imido Complex and Its Reactivity.
Authors L. Maron; X. Han; L. Xiang; C.Alvarez Lamsfus; W. Mao; E. Lu; X. Leng; Y. Chen
Journal Chemistry
DOI 10.1002/chem.201703905
Abstract

Dihydrogen is easily activated by a scandium terminal imido complex containing the weakly coordinated THF. The reaction proceeds via a 1,2-addition mechanism, which is distinct from ?-bond metathesis mechanism reported to date for rare-earth metal mediated H2 activation. This reaction yields a scandium terminal hydride, which is well structurally characterized, being the first one to date. The reactivity of this hydride is reported with unsaturated substrates, further enlightening the existence of the terminal hydride complex. Interestingly, the H2 activation can be reversible. DFT investigations further shed light on the mechanistic aspects of the reactivity of the scandium anilido-terminal hydride complex with PhNCS but also on the reversible H2 activation process.

Citation L. Maron; X. Han; L. Xiang; C.Alvarez Lamsfus; W. Mao; E. Lu; X. Leng; Y. Chen.Synthesis of Scandium Terminal Hydride From H2 Activation by Scandium Terminal Imido Complex and Its Reactivity.. Chemistry. 2017. doi:10.1002/chem.201703905

Related Elements

Scandium

See more Scandium products. Scandium (atomic symbol: Sc, atomic number: 21) is a Block D, Group 3, Period 4 element with an atomic weight of 44.955912. The number of electrons in each of Scandium's shells is [2, 8, 9, 2] and its electron configuration is [Ar] 3d1 4s2. Scandium Bohr Model The scandium atom has a radius of 162 pm and a Van der Waals radius of 216 pm.Scandium was predicted by Dmitri Mendeleev in 1871 and actually discovered and isolated by Lars Nilson in 1879. One of the transition metals, scandium has a silvery-white appearance in its elemental form which oxidizes to yellow or pinkish upon contact with air. Elemental ScandiumIt is occasionally included in the classification of the rare earth elements. Scandium is found in concentrated amounts in the minerals euxenite, gadolinite and thortveitite however, due to the difficulties in the preparation of metallic scandium, global trade of the pure metal is very limited. The origin of the name scandium comes from the Latin word 'scandia' meaning Scandinavia.

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