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Thorium
Thorium information, including safety data and its properties, research, applications and other useful facts are discussed below. Scientific facts such as the atomic structure, ionization energy, abundance on Earth, conductivity and thermal properties are included.

Thorium is a lanthanide (rare earth) material with potential nuclear power applications. Thorium is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. It is presently used as a tungsten coating in electronic parts due to its high emission factor. Thorium in the form of its fluoride and oxide is used in advanced optic applications for its high refractive index. It is also used in several other high temperature glass applications, such as in the mantle of lamps and to produce crystal growth crucibles and ampules.

Thorium facts, including appearance, CAS #, and molecular formula and safety data, research and properties are

 

  Hydrogen                                 Helium
  Lithium Beryllium                     Boron Carbon Nitrogen Oxygen Fluorine Neon
  Sodium Magnesium                     Aluminum Silicon Phosphorus Sulfur Chlorine Argon
  Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Hydrogen Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton
  Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon
  Cesium Barium Cerium Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury Thallium Lead Bismuth Polonium Astatine Radon
                                     
      Cerium Praseodymium Neodymium Promethium Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium    
      Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawerencium    


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available for many specific states, forms and shapes on the product pages listed to the left. Elemental or metallic forms include pellets, rod, wire and granules for evaporation source material purposes. Nanoparticles and nanopowders provide ultra high surface area which nanotechnology research and recent experiments demonstrate function to create new and unique properties and benefits.

Oxides are available in forms including powders and dense pellets for such uses as optical coating and thin film applications. Oxides tend to be insoluble. Fluorides are another insoluble form for uses in which oxygen is undesirable such as metallurgy, chemical and physical vapor deposition and in some optical coatings. Thorium is available in soluble forms including chlorides, nitrates and acetates. These compounds are also manufactured as solutions at specified stoichiometries.

Thorium is a Block F, Group 3, Period 7 element. The electronic configuration is [Rn] 6d2 7s2. In its elemental form thorium's CAS number is 7440-29-1. The thorium atom has a radius of 179.8.pm and it's Van der Waals radius is 200.pm.

All elemental metals, compounds and solutions may be synthesized in ultra high purity (e.g. 99.999%) for laboratory standards, advanced electronic, metallurgy and optical materials and other high technology advantages. Information is provided for stable (non-radioactive) isotopes. Organo-Metallic Thorium compounds are soluble in organic or non-aqueous solvents. See Analytical Services for information on available certified chemical and physical analysis techniques including MS-ICP, X-Ray Diffraction, PSD and Surface Area (BET) analysis.

Thorium was first discovered by Jons Berzelius in 1828.

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Abundance. The following table shows the abundance of thorium and each of its naturally occurring isotopes on Earth along with the atomic mass for each isotope.

Isotope
Atomic Mass
% Abundance on Earth
Th-229
229.031755
*
Th-230
232.038050
100

Safety Data. The safety data for thorium metal, nanoparticles and its compounds can vary widely depending on the form. For potential hazard information, toxicity, and road, sea and air transportation limitations, such as DOT Hazard Class, DOT Number, EU Number, NFPA Health rating and RTECS Class, please see the specific material or compound referenced in the left margin.

Ionization Energy. The ionization energy for thorium (the least required energy to release a single electron from the atom in it's ground state in the gas phase) is stated in the following table:

1st Ionization Energy
608.51 kJ mol-1
2nd Ionization Energy
1109.59 kJ mol-1
3rd Ionization Energy
1929.72 kJ mol-1

Conductivity. As to thorium's electrical and thermal conductivity, the electrical conductivity measured as to electrical resistivity @ 20 ºC is 13 μΩcm and its electronegativities (or its ability to draw electrons relative to other elements) is 1.3. The thermal conductivity of thorium is 54 W m-1 K-1.

Thermal Properties. The melting point and boiling point for thorium are stated below. The following chart sets forth the heat of fusion, heat of vaporization and heat of atomization.

Heat of Fusion
19.2 kJ mol-1
Heat of Vaporization
513.67 kJ mol-1
Heat of Atomization
598.65 kJ mol-1

 
Formula Atomic Number Molecular Weight Electronegativity (Pauling) Density Melting Point
Boiling Point
Vanderwaals radius
Ionic radius Energy of first ionization
Th 90 232.04 g.mol -1 1.3 11.72 g.cm-3 at 20 °C 1750 °C 4790 °C 200.pm 0.110 nm (+4) 608.51 kJ.mol-1

PRODUCT CATALOG UK Operations Submicron & Nanopowder Tolling Ultra High Purity Sputtering Target Crystal Growth Rod, Plate, Powder, etc. Foil
 
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Recent Research & Development for Thorium

  • Retention studies on uranium, thorium and lanthanides with amide modified reverse phase support and its applications.
    J Chromatogr A. 2007 Jan 10; [Epub ahead of print]

  • Age dependence of natural uranium and thorium concentrations in bone.
    Health Phys. 2007 Feb;92(2):119-26.


  • NATURAL RADIOACTIVITY INTAKE INTO WHEAT GROWN ON FERTILIZED FARMS IN TWO DISTRICTS OF PAKISTAN.
    Radiat Prot Dosimetry. 2006 Dec 21; [Epub ahead of print].

  • Enhanced diffusion of Uranium and Thorium linked to crystal plasticity in zircon.
    Geochem Trans. 2006 Dec 20;7:10.


  • Sequential separation of lanthanides, thorium and uranium using novel solid phase extraction method from high acidic nuclear wastes.
    J Hazard Mater. 2006 Nov 18; [Epub ahead of print]


  • Measurement of the concentration of radon gas in the Toirano's caves (Liguria).
    Ann Chim. 2006 Sep-Oct;96(9-10):515-24.


  • Application of extraction chromatography to the separation of thorium and uranium dissolved in a solution of high salt concentration.
    J Chromatogr A. 2007 Jan 26;1140(1-2):163-7. Epub 2006 Dec 11.

  • Effect of soil humic and fulvic acids, pH and ionic strength on Th(IV) sorption to TiO(2) nanoparticles.
    Appl Radiat Isot. 2006 Dec 6; [Epub ahead of print]


  • The coordination of perrhenate and pertechnetate to thorium(IV) in the presence of phosphine oxide or phosphate ligands.
    Dalton Trans. 2006 Dec 28;(48):5734-42. Epub 2006 Oct 10.


  • Sorption of Th (IV) to silica as a function of pH, humic/fulvic acid, ionic strength, electrolyte type.
    Appl Radiat Isot. 2007 Feb;65(2):155-63.

 

 

 

 

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